The reactivity of dodecoxy-terminated Si(111) surfaces with aqueous acids and bases was investigated using Fourier transform infrared (FTIR) absorption spectroscopy. The monolayers
were formed by the reaction of hydrogen-terminated Si(111) surfaces with dodecyl aldehyde at elevated temperature. The functionalized surfaces were then reacted with 1 M solutions of prototypical
strong acids and bases. Although little degradation was seen in acid media, the alkaline solutions degraded the monolayers significantly.
Publisher
Cornell Center for Materials Research
Date
2007-08-29
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Support for the CCMR is provided through the NSF Grant DMR 0520404, part of the NSF MRSEC Program. Additional support is provided by Cornell University, the State of New York, and
by industrial sources.