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View Journal Article: Synthesis, Characterization and Evaluation of Urethane Derivatives of BIS-GMA

Citation: Khatri, C. A., Antonucci, J. M., Stansbury, J. W. and Schultheisz, C. R. (2000). Synthesis, Characterization and Evaluation of Urethane Derivatives of BIS-GMA. ACS Polymer Preprints 41 (2). 1724-1725.
Collection: Polymer Publications  
 
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Title Synthesis, Characterization and Evaluation of Urethane Derivatives of BIS-GMA
Author(s) Khatri, C. A.
Antonucci, J. M.
Stansbury, J. W.
Schultheisz, C. R.
Keyword(s) conversion
hydrophobicity
polymerization shrinkage
synthesis
urethane methacrylates
viscosity
Abstract/Summary In this study, we have reacted Bis-GMA with mono-functional alkyl isocyanates (RNCO) of varying chain length. The resulting urethane group is known to form weaker hydrogen bonds compared to the hydroxyl group but is expected to have higher cohesive energy density than ester or ether linkages. These urethane derivatives of Bis-GMA are expected to have much lower viscosities and water uptake than Bis-GMA and exhibit higher conversion of vinyl groups without excessively increasing polymerization shrinkage of dental resin systems.
Publisher American Chemical Society
Date 2000-01-01
Copyright Notice http://www.nist.gov/public_affairs/disclaim.htm
Journal ACS Polymer Preprints
Volume 41
Pages 1724-1725
Issue 2
Copyright Agreement on
Additional Notes ACS Polymer Preprints 2000; 41(2): 1724-1725.; Sponorship: This research work is supported by NIST / NIDCR Interagency Agreement Y1-DE-7006-0.
 
 
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