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View Journal Article: Thermal and Flammability Properties of a Silica-Poly(methylmethacrylate) Nanocomposite

Citation: Kashiwagi, T., Morgan, A. B., Antonucci, J. M., VanLandingham, M. R., Harris, R. H., Awad, W. H. and Shields, J. R. (2003). Thermal and Flammability Properties of a Silica-Poly(methylmethacrylate) Nanocomposite. Journal of Applied Polymer Science 89 (8). 2072-2078.
Collection: Polymer Publications  
 
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Title Thermal and Flammability Properties of a Silica-Poly(methylmethacrylate) Nanocomposite
Author(s) Kashiwagi, T.
Morgan, A. B.
Antonucci, J. M.
VanLandingham, M. R.
Harris, R. H.
Awad, W. H.
Shields, J. R.
Keyword(s) composite
colloids
degradation
free radical polymerization
flammability
monomer
polymer
silica
nanocomposite
microstructure
Abstract/Summary PMMA, poly(metheylmethacrylate), nanocomposites were made by in situ radical polymerization of MMA, methylmethacrylate, with colloidal silica (ca. 12 nm) to study the effects of nanoscale silica particles on the physical properties and flammability properties of PMMA. Transparent samples resulted and the dispersity of the particles was examined by transmission electron microscopy and atomic force microscopy. The addition of nanosilica particles (13% by mass) did not significantly change the thermal stability, but it made a small improvement in modulus, and it reduced the peak heat release rate roughly 50%. Last, the flame-retardant mechanism provided by the addition of nanosilica particles in PMMA is discussed.
Publisher Wiley Periodicals, Inc.
Date 2003-01-01
Copyright Notice Array
Journal Journal of Applied Polymer Science
Volume 89
Pages 2072-2078
Issue 8
Copyright Agreement on
Additional Notes Journal of Applied Polymer Science 2003; 89(8): 2072-2078. Additional Keywords: poly(metheylmethacrylate)
 
 
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Created: Wed, 01 Nov 2006, 20:51:53 EST Detailed History


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